Facile Construction of Nano-Dimensional Bi Encapsulated in N-Doped Porous Carbon Frameworks for High-Performance Sodium-Ion Hybrid Capacitors

Abstract

As a promising anode candidate for sodium storage, the adhibition of metallic Bi is limited by severe volume expansion and modest conductivity. To solve the issues, optimizing and designing both structures and compositions of Bi-based anodes are highly necessary. Herein, Bi nanoparticles encapsulated in N-doped porous carbon frameworks (Bi@NPC) are synthesized via a facile but efficient chemical blowing method. The size and dispersion of Bi NPs in the interconnected carbon frameworks are accurately adjusted through the control of reaction temperatures and nitrogen doping. Thanks to its attractive structural/componential merits, the optimized Bi@NPC anode shows that an excellent high-rate capability of 207.6 mA h g–1 is achieved at a high rate of 50 A g–1. In addition, it can still present a stable reversible capacity of 243.9 mA h g–1 over 2000 cycles at 10 A g–1. Furthermore, the assembled sodium-ion hybrid capacitors with Bi@NPC as the anode and commercial active carbon as the cathode realize an exceptional energy/power density of 94.2 W h kg–1/200 W kg–1 and a low capacity decay rate of 0.014% per cycle for 2400 cycles at 1 A g–1. The contribution here will guide future design of alloy-type anode materials toward advanced sodium-ion hybrid capacitors.

Operando Studies of Bismuth Nanoparticles Embedded in N, O‐Doped Porous Carbon for High‐Performance Potassium‐Ion Hybrid Capacitor

“…[ 7–9 ] Especially potassium‐ion hybrid capacitors (PIHC), which integrate a battery‐type anode as the negative electrode and capacitive carbon as the positive electrode in an asymmetric manner, combine the best of potassium‐ion batteries (PIBs) and potassium‐ion capacitors (PICs), promising a high‐power output, excellent energy density, and a long cycling life. [ 8,10 ] (De)adsorption of anions on carbonaceous positive electrodes is able to be exploited to increase the cell voltage, boosting further the energy density of the cells. For PIHC, the low solvation/de‐solvation energy of K + grants a fast charge transfer.…”

Coupling of Nd doping and oxygen-rich vacancy in CoMoO4@NiMoO4 nanoflowers toward advanced supercapacitors and photocatalytic degradation

“…20 In order to overcome these issues, researchers have made many attempts, such as material composites, nanostructure design, and elemental doping, to improve the performance of products. [21][22][23] Wu et al 24 successfully doped Co into NiMoO 4 . By controlling the molar ratio of Co and Ni, they achieved changes in the particle size and band structure, resulting in the enhancement of the redox ability of Ni(Co)MoO 4 .…”

Transition Metal Oxides as the Electrode Material for Sodium-Ion Capacitors

“…Therefore, the demand for electrochemical energy storage systems has grown in the market globally. Lithium-ion batteries (LIBs) and supercapacitors (SCs) have been marked significantly in the field of energy storage [Lee et al, 2023;Jo et al, 2023;Li et al, 2023;Liu et al, 2023]. LIBs have a high energy density (Ed) of 150-250 Wh kg -1 , but their power density (Pd) is less than 1000 W kg -1 , which is generally insufficient, and their cycling stability is fairly restricted (1000 cycles).…”