“…The optimum sample's swift charge transfer capacity may be due to the extended conjugated electronic structure of the organic building blocks and the Ni co‐catalyst. Warburg impedance was not found in the low‐frequency zone, confirming the absence of diffusion‐limited electrochemical reaction on the electrode surface 48,49 . The resistance values obtained for Ni@MOP electrocatalysts were listed in Table S2.…”
Section: Resultsmentioning
confidence: 76%
“…Warburg impedance was not found in the low-frequency zone, confirming the absence of diffusion-limited electrochemical reaction on the electrode surface. 48,49 The resistance values obtained for Ni@MOP electrocatalysts were listed in Table S2.…”
Section: Evaluation Of Electrocatalytic Her Activity Of the Mopmentioning
In this study, sulfur-enriched microporous organic polymer (MOP) was prepared using one-pot Shiff-base type polycondensation reaction of thiophendicarboxaldehyde with melamine. With 195.731 m 2 g À1 surface area and 0.047 cm 3 g À1 pore volume, the as-synthesized MOP has a cotton-like morphology and a micropore-dominated pore size distribution. After loading MOP with nickel as a co-catalyst, we demonstrated that the obtained framework could be used as an efficient and robust electrocatalyst for hydrogen evolution reaction (HER) in an alkaline medium with the optimum composite (Ni 2 @MOP) exhibiting a low onset potential of À66 mV. Furthermore, the optimum electrocatalyst showed good stability, delivering 91% faradaic efficiency (FE) after a 3.5 h chronoamperometry experiment.
“…The optimum sample's swift charge transfer capacity may be due to the extended conjugated electronic structure of the organic building blocks and the Ni co‐catalyst. Warburg impedance was not found in the low‐frequency zone, confirming the absence of diffusion‐limited electrochemical reaction on the electrode surface 48,49 . The resistance values obtained for Ni@MOP electrocatalysts were listed in Table S2.…”
Section: Resultsmentioning
confidence: 76%
“…Warburg impedance was not found in the low-frequency zone, confirming the absence of diffusion-limited electrochemical reaction on the electrode surface. 48,49 The resistance values obtained for Ni@MOP electrocatalysts were listed in Table S2.…”
Section: Evaluation Of Electrocatalytic Her Activity Of the Mopmentioning
In this study, sulfur-enriched microporous organic polymer (MOP) was prepared using one-pot Shiff-base type polycondensation reaction of thiophendicarboxaldehyde with melamine. With 195.731 m 2 g À1 surface area and 0.047 cm 3 g À1 pore volume, the as-synthesized MOP has a cotton-like morphology and a micropore-dominated pore size distribution. After loading MOP with nickel as a co-catalyst, we demonstrated that the obtained framework could be used as an efficient and robust electrocatalyst for hydrogen evolution reaction (HER) in an alkaline medium with the optimum composite (Ni 2 @MOP) exhibiting a low onset potential of À66 mV. Furthermore, the optimum electrocatalyst showed good stability, delivering 91% faradaic efficiency (FE) after a 3.5 h chronoamperometry experiment.
“…This evidence clearly indicated that the optimum doping of Ag onto MnO 2 is 7.5 mmol. Moreover, compared with O 2 saturated and unsaturated Ag–MnO 2 -7.5 modified electrode, the peak current of Ag/MnO 2 /GCE was increased dramatically after O 2 saturatation and the peak potential shifted to the more positive value ( Figure 6 c) [ 38 ]. Moreover, for bare GCE and MnO 2 electrode, the onset potential for oxygen reduction is -0.28 V and -0.25 V vs. Ag/AgCl correspondingly.…”
“…Furthermore, the OER performance was evaluated, and the recently published results of the OER are given in Table 2. [78][79][80][81][82][83][84][85][86][87][88][89][90][91][92][93][94][95][96][97] It is obvious that the presented approach is facile, low cost, and efficient in terms of low overpotential, environmental friendliness and scale up for the fabrication of electrocatalyst materials.…”
Section: Oer Half-cell Investigation Of Milky Sap Of Cp-mediated Sco ...mentioning
The preparation of Co3O4 nanostructures by a green method has been rapidly increasing owing to its promising aspects, such as facileness, atom economy, low cost, scale-up synthesis, environmental friendliness, and minimal use of hazardous chemicals.
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