Facile formation of tetrazole–thiolato Pd(ii) and Pt(ii) complexes through deprotonation or oxidative addition using organic tetrazole–thiones

Abstract

Mono or bis(tetrazole-thiolato) Pd(II) or Pt(II) complexes were obtained from dialkyl Pd(II) or Pt(II) complexes with organic tetrazole-thiones (1-aryl or 1-alkyl-1H-tetrazole-5-thiones) via deprotonation. In contrast, equimolar reactions of zerovalent Pt(0)...