Facile hydroboration of (Z)-1-trimethylsilyl-1-alkenes with dichloroborane–dioxane complex: An easy access to gem-dimetalloalkanes containing boron and silicon

Bhat, Narayan G.; Villanueva, Mary A.

doi:10.1016/j.jorganchem.2005.12.043

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Synthesis and Structure of N,N‐Dinitroamidoborane Complexes

Shitov

Tartakovsky

Golovanov

et al. 2017

Chemistry An Asian Journal

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A general approach to the synthesis of borohydride complexes containing one or two dinitroamide fragments has been suggested. Based on a smooth substitution of halide in haloborane or dibromoborane complexes with N,N-dinitroamide salts, this method provides various N,N-dinitroamidoboranes complexes in good yields and in analytically pure form. By means of spectroscopic and computational methods, it was demonstrated that dinitroamidoborane complexes could form as both B,N- and B,O-isomers, which did not interconvert at ambient temperature.

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