Facile immobilization of graphene nanosheets onto PBO fibers via MOF-mediated coagulation strategy: Multifunctional interface with self-healing and ultraviolet-resistance performance

Shao, Qing; Lu, Fei; Xu, Xirong; Huang, Xinghao; Huang, Yudong; Hu, Zhen

doi:10.1016/j.jcis.2020.11.026

Cited by 45 publications

(16 citation statements)

References 50 publications

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“…Due to extraordinary strength-to-weight ratios and high mechanical properties, carbon fiber-reinforced polymer composite (CFRP) materials are widely applied in high-tech fields. 64,65 The BP-PHT thermoset not only possesses exceptional tensile strength and modulus, but also has better toughness and degradation properties than OP-PHT (Fig. 7c).…”

Section: Resultsmentioning

confidence: 99%

Recyclable tough thermosets with an imide-hexahydrotriazine structure

Liu

Wan

et al. 2022

Polym. Chem.

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Section: Resultsmentioning

confidence: 99%

Recyclable tough thermosets with an imide-hexahydrotriazine structure

Liu

Wan

et al. 2022

Polym. Chem.

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“…For the untreated PBO sample, the characteristic peaks at 284.8, 285.7, 286.7, and 288.1 eV represent C−C, C−N, C−O, and CN bonds, respectively. 31 During the acid oxidation, the oxazole ring of PBO polymers undergoes an open-ring reaction, which increases oxygencontaining groups. 32 With the help of D400, CNTs and GO were grafted onto PBO fiber through the condensation reaction between carboxyl groups and amino groups.…”

Section: Resultsmentioning

confidence: 99%

“…Figure shows XPS C 1s spectra and its peak fitting curve of different PBO fibers. For the untreated PBO sample, the characteristic peaks at 284.8, 285.7, 286.7, and 288.1 eV represent C–C, C–N, C–O, and CN bonds, respectively . During the acid oxidation, the oxazole ring of PBO polymers undergoes an open-ring reaction, which increases oxygen-containing groups .…”

Section: Resultsmentioning

confidence: 99%

Poly(p-phenylene benzobisoxazole) Fiber/Epoxy Composites Reinforced with Carbon Nanotubes and Graphene Oxide for Enhanced Interfacial Adhesion and Mechanical Strength

Liu

Chen

et al. 2021

ACS Appl. Nano Mater.

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Herein, CNT and GO were used to construct the multiscale-reinforced interphase of the PBO fiber composite for exploring their action in the interfacial adhesion and overall mechanical performance. Compared to the grafting CNT or GO, the cografting of CNT/GO shows better interfacial regulation including increased surface wettability of fiber, enhanced interfacial adhesion, and improved failure resistance of the interfacial region. The interface structure of GO@CNT endows the composites with significantly improved interfacial adhesion. The IFSS and ILSS increased by 20.75 (or 31.42)% and 32.85 (or 51.64)%, respectively, compared to the interphase of CNT (or GO). The reinforcing effect of CNT/GO also leads to the improvement in mechanical features, interfacial load transfer, local stress elimination, and crack propagating inhibition of the interphase. The impact strength of PBO−GO@CNT composite increased from 67.25 to 106.78 kJ/m 2 . The strategy of interfacial engineering developed by our study will play a crucial role in the field of structural materials, flexible sensors, supercapacitors, catalysts, and energy conversion and storage materials.

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“…To improve the mechanical properties of organic films, the methods of cross-linking, nano-materials mixing, and structure assembly in polymers have been mostly considered. [30][31][32] Inspired by the impressive adhesion and robust properties of nacrelike "brick-and-mortar" structures, biomimetic-assembly would be an efficient way to obtain high-performance protective films due to intrinsic properties and high level of ordering of nanobuilding blocks. [33] Zlotnikov et al used polystyrene sulfonate sodium salt and polyallylamine hydrochloride to fabricate a multilayer organic film with a thickness of 14 nm through a selfassembly method.…”

Section: Introductionmentioning

confidence: 99%

Robust, Superhydrophobic, and Self‐Healing Films with Hierarchical Nacre Mimetics: A High‐Efficiency and “Green” Route Based on Solvent‐Free Polyurethane/Modified Graphene Oxide Composites

Luo

Qin

Feng

et al. 2022

Macro Materials & Eng

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Superhydrophobic and self-cleaning materials have attracted tremendous attention because of their broad applications. However, it is still challenging to develop excellent films exhibiting both reparable superhydrophobic and robust mechanical properties by an environmentally friendly method. Inspired by a natural nacre structure, the novel multi-layered inorganic-organic films consisting of n-octadecylamine-modified graphene oxide (NGO) and solvent-free self-healing polyurethane synthesized by Diels-Alder reaction (SFPU-DA) are demonstrated. Through the layer-by-layer assembly technology, super-hydrophobic and self-repairing solvent-free polyurethane composite films (NGO/SFPU-DA films) are prepared. The NGO/SFPU-DA composite films exhibit healing of surface creases and cracks within 120 s at 120 °C. Meanwhile, the contact angle and sliding angle of the films can be as high as 151°and 8°, respectively. Noticeably, even after 21 times of rubbing, the superhydrophobicity of the obtained films does not significantly reduce. In addition, the tensile strength and peel strength of NGO/SFPU-DA films can reach 22.6 MPa and 88.6 N/30 mm. Moreover, the steel coated with NGO/SFPU-DA films exhibits lower corrosion current density and better corrosion resistance than the single NGO/SFPU-DA film and uncoated steel. The method may provide an effective way to obtain excellent self-cleaning materials with long service life.

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Facile immobilization of graphene nanosheets onto PBO fibers via MOF-mediated coagulation strategy: Multifunctional interface with self-healing and ultraviolet-resistance performance

Cited by 45 publications

References 50 publications

Recyclable tough thermosets with an imide-hexahydrotriazine structure

Recyclable tough thermosets with an imide-hexahydrotriazine structure

Poly(p-phenylene benzobisoxazole) Fiber/Epoxy Composites Reinforced with Carbon Nanotubes and Graphene Oxide for Enhanced Interfacial Adhesion and Mechanical Strength

Robust, Superhydrophobic, and Self‐Healing Films with Hierarchical Nacre Mimetics: A High‐Efficiency and “Green” Route Based on Solvent‐Free Polyurethane/Modified Graphene Oxide Composites

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