Facile one pot synthesis of a range of reversible addition–fragmentation chain transfer (RAFT) agents

Skey, Jared; O’Reilly, Rachel K.

doi:10.1039/b804260h

Cited by 181 publications

(178 citation statements)

References 31 publications

Supporting

Mentioning

172

Contrasting

Unclassified

Order By: Relevance

“…108 [275] St [71,275] (St-b-BA) [275] S S S 109 [284] S S S 110* [283] BA [70] tBA [283] AM [285] St [70,286] St-b-NIPAM [286] tBA [284] St [284] tBA-b-St [284] St-b-BA [284] St/AA [287] St/AA-b-St [287] St/MAH/NVP [288,289] (Continued) [290] 111b RЈ ϭ C 2 H 5 [290] 111c RЈ ϭ i C 3 H 7 [290] 111d RЈ ϭ t C 4 H 9 [290] 111e RЈ ϭ CH 2 Ph [290] 112 [290] S…”

Section: *unclassified

“…MMA [27] 146 [283] S S Ph C 12 H 25 S CO 2 C 2 H 5 tBA [283] 147 [27] S S Ph C 12 H 25 S CO 2 H MMA [27] 148 [335] NIPAM [335] 149 [283] 150 [336,337] S S C 6 H 13 S St [336,337] CMS [336] 151* [338] S S C 12 H 25 S…”

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

“…BA [334] EHA [334] LA [334] St [334] BA-b-EHA [334] BA-b-LA [334] 143 [283] MMA [8] 145 [27] S S Ph CN C 12 H 25 S…”

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

“…MMA [296] St [296] 128* [283] S S C 12 H 25 S CO 2 H AA [91] CA [297] tBA [298] MA [299] (BMA) [300] (BMA) [300] CMA [301] MMA [122,283] (MMA) [122] BAM [302] DEAM [302,303] DMAM [302,303] EMAM [302,303] NIPAM [302][303][304][305][306] PAM [302,306] MVK [307] PVK [307] 297 [308] tBS [276] CMS [309] HMS [309] St [91,300,309] (St) [300] 4VP [310] Ip [311] 320 [312] 325 [100] 327 [309] 331 [313] 332 [313] NVP [103] 331-b-St [313] tBA-b-Ip [298] tBA-b-St [298] tBA-b-IP-b-St …”

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

See 3 more Smart Citations

Living Radical Polymerization by the RAFT Process - A Second Update

Moad¹,

Rizzardo²,

Thang³

2009

Aust. J. Chem.

906

720

View full text Add to dashboard Cite

This paper provides a second update to the review of reversible deactivation radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem. 2005, 58, 379-410). The first update was published in November 2006 (Aust. J. Chem. 2006, 59, 669-692). This review cites over 500 papers that appeared during the period mid-2006 to mid-2009 covering various aspects of RAFT polymerization ranging from reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses and a diverse range of applications. Significant developments have occurred, particularly in the areas of novel RAFT agents, techniques for end-group removal and transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

show abstract

Section: *unclassified

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

“…BA [334] EHA [334] LA [334] St [334] BA-b-EHA [334] BA-b-LA [334] 143 [283] MMA [8] 145 [27] S S Ph CN C 12 H 25 S…”

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

Section: S S Cn C 2 H 5 Smentioning

confidence: 99%

See 2 more Smart Citations

Living Radical Polymerization by the RAFT Process - A Second Update

Moad¹,

Rizzardo²,

Thang³

2009

Aust. J. Chem.

906

720

View full text Add to dashboard Cite

show abstract

“…O'Reilly and Hansell [474] have published on the synthesis of multifunctional trithiocarbonates The general conditions involve the use of acetone as solvent and phosphate as base as reported in a previous study from the same group. [552] B. Reaction of a dithiochloroformate or a thiocarbonyl-bisimidazole with nucleophiles.…”

mentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process – A Third Update

2012

View full text Add to dashboard Cite

This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(¼S)SR) by a mechanism of reversible addition-fragmentation chain transfer ( Chem. 2009Chem. , 62, 1402. This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

show abstract

Telechelic Polymers

Pröll

Nuyken

2018

Encyclopedia of Polymer Science and Technology

View full text Add to dashboard Cite

This article presents commonly used synthetic routes and strategies toward polymers or oligomers with well‐defined functional end groups, specified as telechelics. It is to mention that mainly literature since 2000 until present has been considered. Telechelic polymers with diverse end groups are available via anionic and cationic polymerization as well as via controlled radical polymerization, including nitroxide‐mediated radical polymerization and atom transfer radical polymerization. Furthermore, metathesis strategies such as ring‐opening metathesis polymerization and acyclic diene metathesis are presented. In addition, selected examples using chain scission to form such well‐defined functionalities are described. Finally, step‐growth polymerization and the synthesis of macromolecular telechelics are outlined.

show abstract

Facile one pot synthesis of a range of reversible addition–fragmentation chain transfer (RAFT) agents

Abstract: The application of a universal synthetic strategy for the high yielding and facile synthesis of a wide range of functional RAFT agents including trithiocarbonates, xanthates and dithiocarbamates is described.

Cited by 181 publications

References 31 publications

Living Radical Polymerization by the RAFT Process - A Second Update

Living Radical Polymerization by the RAFT Process - A Second Update

Living Radical Polymerization by the RAFT Process – A Third Update

Telechelic Polymers

Contact Info

Product

Resources

About