2024
DOI: 10.1021/acs.chemmater.4c00224
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Facile Preparation of Tunable Polyborosiloxane Networks via Hydrosilylation

Colton A. D’Ambra,
Patrick T. Getty,
Taejun Eom
et al.

Abstract: Polyborosiloxanes are used in a variety of fields due to their unique dynamic properties. Traditionally, cross-linked polyborosiloxanes are prepared by incorporating boric acid into siloxane prepolymers, a process that is timeconsuming, energy intensive, and challenging due to reagent immiscibility. Here, we report a versatile synthetic method to rapidly cure polyborosiloxane networks via hydrosilylation of chain end or backbone functionalized polydimethylsiloxane (PDMS) derivatives with an inexpensive triviny… Show more

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