Facile Rearrangement of the 6,11‐Diphenyldibenzo[b,f][1,4]diazocine Skeleton into a Substituted 2‐(2‐Aminophenyl)‐1,3‐diphenylisoindole via Anomalous Carbo­lithiation or Hydrolithiation: Corroboration of Operative SET Processes

Abstract

In memory of our late colleague and friend, Wei Liu (1982-2014)

A Simple and Efficient Synthesis of Tertiary Alcohols via Ta2O5- Catalyzed Barbier-Grignard Addition of Unactivated Aryl Bromides to Aryl Acids

“…而 CuBr、 纳米 CuO 和 Cu 2 O 等其他铜催化剂催化反应获得接近 60%的收率(表 1, Entries 8～10), 当使用 Nb 2 O 5 和 Ta 2 O 5 作 催 化 剂 时 , 反 应 收 率 分 别 继 续 被 提 高 到 70% 和 79% (表 1,Entries 11,12). 以 Ta [16] , Ta 三 苯 基 甲 醇 (4a) [17] : 白 色 固 体 , m.p. 163.8 ～ 164.4 ℃(文献值 m.p.…”

Construction of Bisindolines via Oxidative Coupling Cyclization

“…However, only a few approaches have been developed to synthesize bisindolines in an intramolecular manner . These methods are needed to prepare precursors such as cyclic bisimines, trans -2,2′-diaminostilbenes, or vicinal diamines for further intramolecular reactions, indicating that each final product requires at least two steps (Figure A) . Therefore, it is very necessary to development of new methodologies to synthesized bisindolines via intermolecular reaction. , …”