“…For one thing, the incorporation of hydrophobic groups can improve the stability of silica membranes under hydrothermal conditions, such as octyl [ 11 ], phenyl [ 12 ], alkylamine [ 13 ], methyl [ 14 , 15 ], perfluorodecyl [ 16 ], etc., which effectively reduce the Si–OH concentration on the surface of silica membrane materials, thereby reducing the physical adsorption of water molecules and enhancing the hydrophobicity of silica membranes. For another, further improvement of hydrothermal stability of silica membranes have been researched by introducing different types of inorganic metal/metal oxides, such as aluminum [ 17 ], zirconium [ 18 ], nickel [ 19 , 20 ], titanium [ 21 ], cobalt [ 22 , 23 ], palladium [ 24 , 25 ], magnesium [ 26 ], niobium [ 27 ], PdCo [ 28 ], FeCo [ 29 ], etc. They were all added in the process of sol synthesis, which produced great beneficial effects.…”