Thermal expansion behavioro fC NT/Ag nanocompositeIn the present study, the molecular level mixingmethod has been extended to fabricate carbon nanotubeb ased silver nanocomposite. Here, the influence of types of carbon nanotubes and theirf unctionalization on the coefficient of thermale xpansion was examined.C ovalently and noncovalently functionalized single wall as well as multiwall carbon nanotubes were used in the synthesis process. The microstructural features of the compositerevealed that the carbon nanotubes decoratedwith silver nanoparticles were dispersed embedded and anchored in the silver matrix.Experimental results confirmedthat the coefficient of thermal expansion of the composite reduces in relation to that of pure silver, with increasingcontent of carbon nanotubes in the silver matrix.T he thermal expansion of nanocomposites, up to 6volumepercent of nanotubes, reduces to 50 -60 %t hat of pure silver. However, more reduction in thermal expansion of silver nanocomposite with single wall carbon nanotube than with multiwall nanotubes has been observed,w hich is correlated withh igh aspect ratio and large effective surface area of single wall nanotubes. Moreover, covalently functionalized multiwall nanotubes exhibit more reinforcing effect than non-covalently functionalized. We believe that strong bondingbetween carbon nanotubes and metal matrix due to covalent functionalization is responsible foreffective reduction in thermal expansion.