“…The phase of porous Fe 3 O 4 NPs and floral‐like magnetic Fe 3 O 4 @MnO 2 composite material were analyzed by using XRD. The XRD pattern of pure Fe 3 O 4 are shown Figure (a), including the diffraction peaks of pure Fe 3 O 4 (62.8°, 53.7°, 57.1°43.3°, 37.3°, 35.7°, 30.1°, and 18.3°) corresponding to (440), (511), (422), (400), (222), (311), (220) and (111) Bragg reflections, respectively . As shown in Figure (a), there are no extra diffraction peaks, indicating that the as‐synthesized porous Fe 3 O 4 NPs have high purity.…”