Facile Synthesis of a High Performance NiPd@CMK‐3 Nanocatalyst for Mild Suzuki‐Miyaura Coupling Reactions

Abstract

pressure. The conversion rate of 4-bromoanisole was determined using gas chromatography-mass (GC-MS) spectrometry.Characterization High resolution transmission electron microscopy (TEM) analysis was performed using a Tecnai TF30 ST and a Titan Double Cs corrected TEM (Titan cubed G2 60-300). Energydispersive X-ray spectroscopy (EDS) elemental mapping data were collected using a higher efficiency detection system (Super-X detector). High power powder-XRD (Rigaku D/MAX-2500, 18 kW) was also used for the analysis. N 2 -sorption isotherms were obtained at 77 K with a Tristar II 3020 surface area analyzer.

Monomer Self‐Deposition for Ordered Mesoporous Carbon for High‐Performance Supercapacitors

“…[2] In particular,o rdered mesoporousc arbons( OMCs) are of interest owing to their ordered mesoporousc hannels, high surface area, and easy modification. [3] In recent years, OMCs have received extensive attention in the field of electrochemical energy storage, especially for supercapacitors. [4] The mesoporous structure can improve the high-speed transfer of charges, ensuring high rate performance, and providem ore active sites with the high surface area, increasingt he electrochemical capacity.…”

“…[6] Compared with the soft-template method, the hard-template method is one of the most practical and effective approaches to control the porous structurea nd morphologyo fO MCs and thus has obtainedw ide attention.H owever,i nt he hard-template method, multiple steps are alwaysr equired. [3,7] Typically,s olvents such as ethanol, acetone, N,N-dimethylformamide, tetrahydrofuran, or water are necessary for assemblyo ft he carbon precursors in the hard-template channels by infiltration or im-pregnation. Unfortunately,o rganic solvents are harmful to the environment.…”