“…All spectra are similar and show two distinct zones: one strong optical absorption zone in the range 270-400 nm, which is attributed to the transition from the VBM (predominant O(2p) states) to the CBM (predominant Sn(5s,p)). Wide and less intense bands are then observed around 500 nm that can be assigned to carbonate-type impurities (known to absorb in that region 35 ). The amplitude of these bands decreases with the increase of xAl Sn , consistently with the progressive decrease of the amount of SrCO 3 impurity.…”
“…All spectra are similar and show two distinct zones: one strong optical absorption zone in the range 270-400 nm, which is attributed to the transition from the VBM (predominant O(2p) states) to the CBM (predominant Sn(5s,p)). Wide and less intense bands are then observed around 500 nm that can be assigned to carbonate-type impurities (known to absorb in that region 35 ). The amplitude of these bands decreases with the increase of xAl Sn , consistently with the progressive decrease of the amount of SrCO 3 impurity.…”
“…Many compounds are being synthesized with chemistry-sensors, among the heterocyclic compounds, the 5 membered ring compound 4-Amino-1,2,4-Triazole-3-thiol derivative has an amine group and thiol group, so the amine group reacts easily with aldehyde to become a Schiff base (Imine) group and can be used as a chemosensor. Schiff base is synthesized by simple experiments under simple conditions and is a good functional group for use in chemical sensors because of the simple structure of the double bond between nitrogen and carbon and the unshared electron pair of nitrogen [13]. In addition, there are more opportunities to bind with ions due to the sulfur in the thiol group.…”
Section: Introductionmentioning
confidence: 99%
“…These reagents used without further puri cation. 13 C and 1 H NMR were measured at 126 MHz, 500 MHz, and 400 MHz with a Bruker Avance (Germany) NMR Spectrophotometer using DMSO-d 6 . Mass spectrometry (LC-MS) was measured using a 2975/ZQ2000 (waters) spectrometer.…”
We have prepared Schiff base functionalized 1,2,4-Triazole and Pyrene derivatives for selective, sensitive, and naked eye colorimetric detection of Cu2+ in the mixed organic- aqueous media. Amongst the 18 different metal ions studied for absorption and fluorescence titration, only Cu2+ ion encourages the modification in spectral properties of Schiff base functionalized 1,2,4-Triazole and Pyrene Probe. The stoichiometric ratio of the Probe-Cu2+ complex was determined to be 2:1 according to Job’s plot. The lower detection limit estimated for Cu2+ is 0.234 nM which shows excellent sensitivity and selectivity of the present analytical method towards detection of Cu2+ ion in the mixed organic-aqueous media. The present approach has been successfully utilized for the quantitative determination of Cu2+ ion from environmental aqueous solution.
“…Carbonate ions in water can have three forms: carbonate ion (CO3 2-), hydrogen carbonate (HCO3 -) and carbon dioxide (CO2), and there is an equilibrium among them. Many methods have been proposed for detecting carbonate, for example optical sensors, titration, ion chromatography and others [5][6][7]. However, these methods are usually conducted in a laboratory and require expensive equipment, complex sample treatment and technical expertise.…”
A novel disposable all-solid-state carbonate-selective electrode based on a screen-printed carbon paste electrode using poly(3-octylthiophene-2,5-diyl) (POT) as an ion-to-electron transducer has been developed. The POT was dropped on the reaction area of the carbon paste electrode covered by the poly(vinyl chloride) (PVC) membrane, which contains N,N-Dioctyl-3α,12α-bis(4-trifluoroacetylbenzoyloxy)-5β-cholan-24-amide as a carbonate ionophore. The electrode showed a near-Nernstian slope of-27.5mV/decade with a detection limit of 3.6*10-5 mol/L. Generally, the detection time was 30s. Because these electrodes are fast, convenient and low in cost, they have the potential to be mass produced and used in on-site testing as disposable sensors. Furthermore, the repeatability, reproducibility and stability have been studied to evaluate the properties of the electrodes. Measurement of the carbonate was also conducted in human blood solution and achieved good performance.
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