“…18,23 In order to address the above issues and further enhance the performance of the electrochemical capacitors, scientic researchers have focused their attention on developing various methods to enlarge the space between the graphene sheets and open the bandgap of the nal materials, such as introducing the intercalation reagents, creating the porous structure, constructing the three dimensional (3D) matrix of graphene-based materials, and heteroatom doping. 7,10,11,24 The feasibility of above mentioned strategies have been proven by vast amounts of representative works, such as graphene/MnO 2 , graphene/Co 3 O 4 , graphene/ polypyrrole, boron and nitrogen doped graphene and so on. 21,[25][26][27][28] However, to the best of our knowledge, few researches have been presented about the polymer or metal-free carbon materials with relatively high specic capacitance, which will limit their further application in exible and ultralight electronic eld.…”