Facile synthesis of novel graphene sponge for high performance capacitive deionization

Abstract

Capacitive deionization (CDI) is an effective desalination technique offering an appropriate route to obtain clean water. In order to obtain excellent CDI performance, a rationally designed structure of electrode materials has been an urgent need for CDI application. In this work, a novel graphene sponge (GS) was proposed as CDI electrode for the first time. The GS was fabricated via directly freeze-drying graphene oxide solution followed by annealing in nitrogen atmosphere. The morphology, structure and electrochemical performance of GS were characterized by scanning electron microscopy, Raman spectroscopy, nitrogen adsorption-desorption, X-ray photoelectron spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The electrosorption performance of GS in NaCl solution was studied and compared with pristine graphene (PG). The results show that due to the unique 3D interconnected porous structure, large accessible surface area and low charge transfer resistance, GS electrode exhibits an ultrahigh electrosorption capacity of 14.9 mg g−1 when the initial NaCl concentration is ~500 mg L−1, which is about 3.2 times of that of PG (4.64 mg g−1), and to our knowledge, it should be the highest value reported for graphene electrodes in similar experimental conditions by now. These results indicate that GS should be a promising candidate for CDI electrode.

Nitrogen-doped carbon nanorods with excellent capacitive deionization ability

“…[1][2][3][4][5][6][7][8][9][10][11][12][13] This technology is proceeded through adsorbing ions into the 20 electric double layer formed at the surface of electrodes when a low direct current potential is applied. This principle of CDI makes it an environmentally-friendly process with good reversibility.…”

MgFe2O4/reduced graphene oxide composites as high-performance anode materials for sodium ion batteries

“…Fig. 4(d) shows the corresponding selected area electron diffrac- [34,35]. The MFO has a relatively small Brunauer-Emmet-Teller (BET) specific surface area of 2.54 m 2 g À1 .…”

Reduced graphene oxide as co-catalyst for enhanced visible light photocatalytic activity of BiOBr

“…Commercial graphite powder was used as the starting reagent for the synthesis of GO via modified Hummers method, as described in our previous works [44]. A certain amount of GO and 0.510 g CTAB were dissolved in 70 ml distilled water, then 0.679 g Bi(NO 3 ) 3 ·5H 2 O was added to the solution under stirring, followed by heated at 60 °C for 30 min.…”