Facile synthesis of Sb³⁺-doped (Bmim)₂InCl₅(H₂O) through a grinding method for light-emitting diodes

Abstract

Organic-inorganic metal hybrid halides (OIMHs) as a new kind of photoelectric materials have gained much attention in recent years because of their excellent performance in solid-state lighting applications. However, the...

Achieving Highly Efficient Orange Emission in Tin (IV)‐Based Metal Halides with Outstanding Anti‐Water Stability Through Antimony Doping and Reasonable Structural Modulation

“…The PLE band became wider and had a distinct red shift with increasing Sb 3+ concentration, which should be caused by the increase in distortion of the [Sn(Sb)Cl 6 ] octahedron or the dipolar interaction between more Sb emission centers. [13] Moreover, this series of Sb 3+ -doped (TBP) 2 SnCl 6 showed variable CIE coordinates because of their different excitation-dependent emission characteristics (Figure S14, Supporting Information), which can change from (0.35, 0.33) under 310 nm excitation to (0.57, 0.41) under 380 nm irradiation.…”