“…8,9 In particular, PCs have gained considerable industrial and academic attention because of their higher energy density than EDLCs and sustainable power density. [10][11][12] Transition metal oxides (TMOs), such as cobalt oxide (Co 3 O 4 ), 4,13 zinc oxide (ZnO), 6,14 ruthenium oxide (RuO 2 ), [15][16][17] vanadium oxide (V 2 O 5 ) 18,19 and manganese dioxide (MnO 2 ), [20][21][22] have been widely employed as materials for PCs. Among the extensively studied PC electrode materials, MnO 2 has received considerable attention owing to its merits such as natural abundance, low work function (4.4 eV), reversible charge-discharge characteristics, cost-effectiveness and high specific theoretical capacitance (1370 F g −1 ).…”