Beyond traditional paper, multifunctional nanopaper has
received
much attention in recent years. Currently, many nanomaterials have
been successfully used as building units of nanopaper. However, it
remains a great challenge to prepare flexible and freestanding metal–organic
framework (MOF) nanopaper owing to the low aspect ratio and brittleness
of MOF nanocrystals. Herein, this work develops a flexible and free-standing
MOF nanopaper with MOF nanowires as building units. The manganese-based
MOF (Mn-MOF) nanowires with lengths up to 100 μm are synthesized
by a facile solvothermal method. Through a paper-making technique,
the Mn-MOF nanowires interweave with each other to form a three-dimensional
architecture, thus creating a flexible and free-standing Mn-MOF nanowire
paper. Furthermore, the surface properties can be engineered to obtain
high hydrophobicity by modifying polydimethylsiloxane (PDMS) on the
surfaces of the Mn-MOF nanowire paper. The water contact angle reaches
130°. As a proof of concept, this work presents two potential
applications of the Mn-MOF/PDMS nanowire paper: (i) The as-prepared
Mn-MOF/PDMS nanowire paper is compatible with a commercial printer.
The as-printed colorful patterns are of high quality, and (ii) benefiting
from the highly hydrophobic surfaces, the Mn-MOF/PDMS nanowire paper
is able to efficiently separate oil from water.