Facilitated ion transfer across oil∣water interfaces. Part III. Algebraic development and calculation of cyclic voltammetry experiments for the formation of a neutral complex

Ag+ transfer across the water/1,2-dichloroethane interface facilitated by complex formation with tetraphenylborate derivatives

“…Testing the results described earlier adjusting the model developed by Tomaszewski et al [30] and summarized above show that in the previous experimental conditions Ag + ion is not transferred through the formation of an ion pair with TPBCl − . However, if a reasonable extrapolation is made that Eqs.…”

“…However, recently, Tomaszewski et al [30] analysed a theoretical model for the transfer of ions assisted by charged ligands in the form of ion pairs. The authors showed that the earlier results obtained for ion-transfer assisted by neutral ligands are also valid in the situation of charged ligands, namely for the concentration dependence of the half-wave potential for the case of excess ligand concentration:…”

Investigation of ion-selective electrodes with neutral ionophores and ionic sites by EIS. I. Theory

“…Therefore, in the presence of an ionophore, ionic transfer is facilitated, or assisted [26][27][28] when To simplify the analytical resolution of this problem, two limiting cases are considered ( Fig. 3(a)):…”

Simple Ion Transfer at Liquid|Liquid Interfaces

“…On the basis of this, Girault and co-workers solved diverse kinds of mechanisms. These authors described for the first time the effect of mixed diffusion control of the cation and the ligand on the shape of the voltammograms for the facilitated transfer by formation of a single 1 : 1 complex [472], complex formation of different stoichiometries (1 : 1· · · 1 : 4) that allow the competition between them [473,474], and formation of neutral complexes [475]. Kudo et al [476] started working on the competitive transfer of a twocation mixture assisted by a neutral ligand.…”