With the advancement of Industry 4.0, Time-Sensitive Networking (TSN) has become essential for ensuring prompt and reliable data transmission. As an augmentation of Ethernet, TSN aims to supply services capable of low latency, minimal jitter, and low packet loss for urgent data in decentralized, user-oriented networks. Efficient detection techniques are integral to TSN for swiftly determining the practicability of network configurations, as existing schedulability analysis proves insufficient. This paper delves into the potential of backpropagation neural networks (BPNN) in schedulability analysis efficiency. We optimize BPNN using spearman correlation feature selection combined with a voting ensemble method and Particle Swarm Optimization, forming two models: Spearman-Vote-BPNN and Spearman-PSO-BPNN. Testing on 5,000 network configurations in computer simulations, both models demonstrated high generalization accuracy, around 97.4%. Spearman-Vote-BPNN achieved the fastest training speed at 0.63 seconds and an accuracy of 98.2%. Meanwhile, Spearman-PSO-BPNN showed the highest accuracy (98.5%) with the quickest detection speed (5.6ms). The outcomes of this research significantly advance the efficacy and precision of TSN network configuration detection and establish a formidable groundwork for future scholarly pursuits in this area.