1,4-Dioxane is a
probable human carcinogen and a widely occurring
water contaminant. Cometabolic biodegradation of 1,4-dioxane could
potentially provide a cost-effective and efficient treatment, but
research is needed to establish its viability for water reuse purposes.
The purpose of this study was to compare propane versus tetrahydrofuran
as cometabolites for enhancing the removal of 1,4-dioxane via biologically
active carbon filtration (BAF) as part of a pilot-scale water reuse
system. Removal of 10, 5, 1, and 0.3 μg/L of 1,4-dioxane by
BAF was examined in systems amended with either propane (2 mg/L) or
tetrahydrofuran (25–50 μg/L), receiving the same ozonated,
secondary wastewater effluent. At the lowest influent 1,4-dioxane
concentration (0.3 μg/L), the tetrahydrofuran amended filter
removed on average 58% ± 4% (std dev) of the incoming 1,4-dioxane.
During the same period, the propane amended filter removed on average
74% ± 7% of the incoming 1,4-dioxane and at times degraded the
1,4-dioxane to below the method detection limit of 0.06 μg/L.
This study demonstrates that amending cometabolites prior to BAF is
a feasible treatment technique for removal of 1,4-dioxane occurring
at submicrogram per liter concentrations and thus holds promise for
both potable reuse applications and drinking water treatment.