Modeling of silicon nanocrystals based down-shifter for enhanced silicon solar cell performance J. Appl. Phys. 111, 034303 (2012) Analytical solution for the photocurrent of solar cells with internal reflection J. Appl. Phys. 111, 034502 (2012) On the design and applicability of nanowire solar cells using low-grade semiconductors J. Appl. Phys. 111, 034501 (2012) Fundamental limits in the external quantum efficiency of single nanowire solar cells Appl. Phys. Lett. 99, 263102 (2011) A semi-analytical model for semiconductor solar cells J. Appl. Phys. 110, 123104 (2011) Additional information on J. Appl. Phys. We report on a scanning capacitance spectroscopy (SCS) study on the n þ -p junction of multicrystalline silicon solar cells. We found that the spectra taken at space intervals of $10 nm exhibit characteristic features that depend strongly on the location relative to the junction. The capacitance-voltage spectra exhibit a local minimum capacitance value at the electrical junction, which allows the junction to be identified with $10-nm resolution. The spectra also show complicated transitions from the junction to the n-region with two local capacitance minima on the capacitance-voltage curves; similar spectra to that have not been previously reported in the literature. These distinctive spectra are due to uneven carrier-flow from both the n-and p-sides. Our results contribute significantly to the SCS study on asymmetrical junctions.