We have studied the ionic outcome from the interaction of intense laser light with large argon and xenon clusters. Ions with initial energies of several 100 keV are charge and energy selected using a magnetic deflection time-of-flight mass spectrometer. For argon clusters, Coulomb repulsion is the key process in the explosion mechanism, whereas for xenon we observe a mixture of Coulomb repulsion and hydrodynamic expansion. Coulomb explosion is the preferred decay channel for smaller clusters and it is also responsible for the production of the most energetic ions. Our results can be understood on the basis of a charged sphere model of cluster-sized plasmas. [S0031-9007 (97)05135-1] PACS numbers: 36.40.Vz, 52.40.NkThe development of relatively compact but powerful short pulse lasers has given strong impetus to the study of matter in intense fields. Solid and gaseous targets have been thoroughly investigated and, generally, highly excited states of matter are reported (see, for example, [1]). Recently, since atomic clusters have an intermediate target size, they have captured the attention as a promising means to produce x rays in the keV range [2-4], high particle velocities [5,6] and highly charged ions [6][7][8]. According to Wülker et al.[9] as well as Ditmire and co-workers [10,11], the very energetic states of matter obtained when irradiating clusters are usually interpreted as hot cluster-sized plasmas, efficiently laser heated by inverse bremsstrahlung. Already for intensities of 10 14 W͞cm 2 we have been able to confirm hydrodynamically expanding nanoplasmas with ion energies of several keV [8]. Much higher particle energies reaching up to 1 MeV, obtained after irradiating xenon clusters with 10 16 W͞cm 2 , are also currently attributed to hydrodynamic expansion [5,6]. It should be mentioned that, after the pioneering work by Ehler [12], ion energies of several MeV͞amu have been reported from intense laser irradiation of solids for more than a decade [13,14]. Such energetic particles have been theoretically interpreted as a departure from ideal isothermal expansion due to overheated coronal electrons [15], rarefaction shocks [16], neutralizing return currents [17], ion acoustic turbulences [18], or self-focusing [19]. Most of the theoretical studies on fast ion generation have assumed that the energy distribution in the coronal plasma is described primarily by two temperatures for thermal and hot electrons. Interestingly, two electron temperatures have also been observed from clusters, although electron energies generally did not exceed 3 keV [20]. A difference in three orders of magnitude between ion and electron energies obtained from similar cluster experiments [5,20] could therefore again indicate a failure of the isothermal expansion mechanism. From previous studies on molecules [21] and small clusters [22], a transition regime can be expected for shrinking particle sizes towards a Coulomb explosion mechanism originat-ing from the charge buildup in the system due to electron losses. In such a case, th...