The short material service life of concrete is currently a frequently discussed topic, especially for newly constructed roadways with cement concrete pavement. This early degradation of cement concrete pavement slabs is a major problem that threatens the service life of sub-sections or the entire road. As some partial results demonstrate, a possible cause of this degradation can be seen in the surrounding road environment, namely the possibility of transferring aggressive substances to the concrete pavement slab. This paper is concerned with the verification of the possibility of the penetration of alkalis penetration from the surrounding environment into the concrete pavement slab by simulating the effect of different external conditions and environments.