The demand forecasting of power supply is an indispensable part of China's energy production and consumption. The scale of power grid construction in China has been expanding and the load growth rate has accelerated. Accidents, equipment failures and personnel unemployment often occur in the power system. BP neural network has certain algorithm advantages. Therefore, in order to ensure the safety and demand of residents and buildings, it is necessary to study the emergency materials storage system of power grid based on BP neural network. This paper mainly uses experimental testing and quantitative analysis methods to study the advantages and methods of BP neural network algorithm in the construction and application of electric emergency materials storage system. The experimental data shows that the learning rate of 0.06 selected by BP neural network is the most appropriate in the construction of storage system.