2022
DOI: 10.1002/celc.202200787
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Fe‐Catalyzed Electrochemical C−O Bond Cleavage of Ethers to Access Benzazoles from Ethers and o‐Substituted Anilines

Abstract: An efficient Fe-catalyzed electrochemical synthesis of benzothiazoles from ethers with 2-aminobenzenethiols has been developed through selective CÀ O bond cleavage of ethers under oxidant-free conditions. A set of ethers have been converted to the corresponding 2-aryl-, 2-heteroaryl-, and 2-alkyl-substituted benzothiazoles in moderate to good yields. The method has also been successfully applied to generation of benzimidazoles and benzoxazoles with satisfactory yields and good functional group compatibility.

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“…To quantify the benefits and the advances in terms of the sustainability of our procedure, we compared some green metrics ( E -factor, RME and MRP) calculated for our and other electrochemical procedures. 28…”
Section: Resultsmentioning
confidence: 99%
“…To quantify the benefits and the advances in terms of the sustainability of our procedure, we compared some green metrics ( E -factor, RME and MRP) calculated for our and other electrochemical procedures. 28…”
Section: Resultsmentioning
confidence: 99%