Fe-doped Ni2P nanosheets with porous structure for electroreduction of nitrogen to ammonia under ambient conditions

Guo, Chengying; Liu, Xuejing; Gao, Lingfeng; Kuang, Xuan; Ren, Xiang; Ma, Xiaojian; Zhao, Mingzhu; Yang, Hua; Sun, Xu; Wei, Qin

doi:10.1016/j.apcatb.2019.118296

Cited by 136 publications

(70 citation statements)

References 38 publications

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“…[134] Additionally, benefiting from the Fe incorporation promoting the adsorption of N 2 and the weakening of NN bonds, Gao et al revealed that Fe-doped Ni 2 P owned excellent NRR activity. [135] Sun's group first reported that nonmetal boron phosphide nanoparticles can serve as a high-efficiency N 2 -to-NH 3 catalyst with excellent activity and selectivity. DFT calculation inferred that P in boron phosphide can weaken the NN bond while simultaneously strengthening the BN bond, conductive to exposure more active sites for the NRR catalysis.…”

Section: Nrrmentioning

confidence: 99%

Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies

Liu

Amiinu

et al. 2020

Adv Funct Materials

410

194

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Developing highly efficient and stable electrocatalysts plays an important role in energy-related electrocatalysis fields. Transition-metal phosphides (TMPs) possess a series of advantages, such as high conductivity, earthabundance reserves, and good physicochemical properties, therefore arousing wide attention. In this review, the electrochemical activity origin of TMPs, allowing the rational design and construction of phosphides toward various energy-relevant reactions is first discussed. Subsequently, their unique energy-related electrocatalysis nature toward hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), hydrogen oxidation reaction (HOR), carbon dioxide reduction reaction (CO 2 RR), nitrogen reduction reaction (NRR), urea oxidation reaction (UOR), methanol oxidation reaction (MOR), and others is highlighted. Then, the TMPs' synthetic strategies are analyzed and summarized systematically. Finally, the existing key issues, countermeasures, and the future challenges of TMPs toward efficient energy-related electrocatalysis are briefly discussed.

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Section: Nrrmentioning

confidence: 99%

Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies

Liu

Amiinu

et al. 2020

Adv Funct Materials

410

194

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“…Precious metals [38] and transition metals [39][40][41] are the most widely used pure-metal electrocatalysts for NRR;o wing to their unique d-electrons (8 to 10), noble metalsc an easily adsorb moleculesf or electrochemical reaction and show good adsorption and desorption of new molecules. In addition, noble metal catalysts have excellent chemical durability,c an maintain high catalytic activity,and are more resistant to corrosion in some acid/alkalineelectrolytes.…”

Section: Pure-metalc Atalystsmentioning

confidence: 99%

Current Progress of Electrocatalysts for Ammonia Synthesis Through Electrochemical Nitrogen Reduction Under Ambient Conditions

et al. 2020

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chnology.S he received her bachelor's degree from Jining university,P .R. China. Her research focuses on the electrocatalytic NH 3 synthesis at ambient conditions. Dr.T ingli Ma received her Ph.D. degree in 1999 from Department of Chemistry,F aculty of Science of Kyushu University,J apan. She then joined the National Institute of Advanced Industrial Science and Te chnology (AIST,J apan) as aP ostdoctoral Researcher from 1999 to 2004. She worked as ap rofessor at the Dalian University of Te chnology from 2007-2018. She is working at the Graduate School of Life Science and Systems Engineering Kyushu Institute of Technology,J apan and China Jiliang University.S he leads research teams studying inorganic and organic solar cells, such as dye-sensitized and perovskite solar cells, and other related projects including development of catalysts, hydrogen production, functional dyes, and nano-sized semiconducting materials. Dr.M ah as published more than 200 papers in peer-reviewed journals. Figure 1. Schemeo fe lectrochemicalcell for NH 3 production by electrocatalytic NRR. [30] Published with permission. CopyrightE lsevier,2 018.

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“…Wei et al proposed Fe doped Ni 2 P nanosheets as efficient electrocatalyst for NRR. [195] On carrying out NRR in 0.1 m HCl, 7.95% efficiency was achieved at −0.3 V by producing NH 3 at 88.51 µg h −1 mg cat −1 rate. Hetero atom doping was acknowledged for high NRR activity as it creates bulk surface defects which in turn simultaneously improves the N 2 selectivity and reduce the N 2 fixation energy barrier.…”

Section: Ni Compoundsmentioning

confidence: 98%

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Patil

Wang

2020

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Fe-doped Ni2P nanosheets with porous structure for electroreduction of nitrogen to ammonia under ambient conditions

Cited by 136 publications

References 38 publications

Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies

Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies

Current Progress of Electrocatalysts for Ammonia Synthesis Through Electrochemical Nitrogen Reduction Under Ambient Conditions

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

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