Fe³⁺-substitution effect on the thermal variation of J–E characteristics and DC resistivity of quadruple perovskite CaCu₃Ti₄O₁₂

Abstract

The electrical properties of cubic perovskite series, CaCu3–x Ti4–x Fe2x O12 with x = 0.0, 0.1, 0.3, 0.5, and 0.7, have been studied by employing current density as a function of electric field characteristics registered at different temperatures and thermal variations of direct current electrical resistivity measurements. All of the compositions exhibit strong non-ohmic behavior. The concentration dependence of breakdown field, the temperature at which switching action takes place, and maximum value of current density (J max) has been explained on account of structural, microstructural, and positron lifetime parameters. The highest ever reported value of J max = 327 mA/cm2 has been observed for pristine composition. The values of the nonlinear coefficient advise the suitability of ceramics for low-voltage varistor applications. The Arrhenius plots show typical semiconducting nature. The activation energy values indicate that electric conduction proceeds through electrons with deformation in the system.

Stereopsis‐Inspired 3D Visual Imaging System Based on 2D Ruddlesden–Popper Perovskite

“…[27][28][29][30][31] Moreover, the solution preparation method makes it easier to fabricate flexible large-area film devices. [32][33][34][35][36] Herein, we design a flexible 3D-VIS inspired by binocular stereopsis composed of two subsidiary sensors as shown in Figure 1c, adopting 2D-RPP as photoresponse material, polyimide (PI) film as a flexible substrate, and addressing circuit, of which the structure schematic is shown in Figure 1d. The prepared device arrays show good uniformity with a high switch ratio (≈10 4 ) and responsivity (250 A W −1 ), which are sufficient enough to meet the requirement of image sensing.…”