The effects of argon addition, in the range of 0-20% in a N 2 -CH 4 mixture on the nonequilibrium radiation emitted behind a normal shock wave, have been investigated in a free-piston-driven shock tube. The intensity of spontaneous emission, for the B 2 S + -» X 2 S + electronic transition of CN molecules, is measured at a shock velocity of 5700 m/s propagating in a 200-Pa test gas mixture. Rotational and vibrational temperature profiles in the shock layer are obtained by matching three spectral lines simultaneously recorded in the A*> = 0 band with theoretical spectra calculations. The results show that the nonequilibrium radiation overshoot weakly increases with argon addition, whereas the equilibrium intensity value is not affected. The characteristic relaxation time of radiation is also affected so as to be reduced by argon addition. The vibrational relaxation time for CN molecules is also determined from the temperature profiles, but the accuracy is difficult to assess since the temperatures are weakly dependent functions of ratios of intensities.
Nomenclaturec ~ speed of light F = rotational term, I/cm G = vibrational term, I/cm h ~ Planck's constant, J s / = intensity of spontaneous emission, W/(cm 3 sr) / = rotational quantum number k = Boltzmann's constant, J/K N = number density, I/cm 3 n -electronic quantum number Gtot ~ total partition function q v .^r = Franck-Condon factor R e = electronic transition moment Sj = Honl-London factor T = temperature, K v = vibrational quantum number v = wave number, I/cm Subscripts e = electronic r = rotational v = vibrational Superscripts ' = upper state of transition " = lower state of transition