We have used the narrow 2S 1/2 → 3P 3/2 transition in the ultraviolet (uv) to laser cool and magneto-optically trap (MOT) 6 Li atoms. Laser cooling of lithium is usually performed on the 2S 1/2 → 2P 3/2 (D2) transition, and temperatures of ∼300 μK are typically achieved. The linewidth of the uv transition is seven times narrower than the D2 line, resulting in lower laser cooling temperatures. We demonstrate that a MOT operating on the uv transition reaches temperatures as low as 59 μK. Furthermore, we find that the light shift of the uv transition in an optical dipole trap at 1070 nm is small and blueshifted, facilitating efficient loading from the uv MOT. Evaporative cooling of a two spin-state mixture of 6 Li in the optical trap produces a quantum degenerate Fermi gas with 3 × 10 6 atoms in a total cycle time of only 11 s. The creation of quantum degenerate gases using all-optical techniques [1-4] offers several advantages over methods employing magnetic traps. Optical potentials can trap any ground state, allowing selection of hyperfine sublevels with favorable elastic and inelastic scattering properties. In the case of Fermi gases, the ability to trap atoms in more than one sublevel eliminates the need for sympathetic cooling with another species [5,6], greatly simplifying the experimental setup. All-optical methods also facilitate rapid evaporative cooling since magnetically tunable Feshbach resonances can be employed to achieve fast thermalization.There are, however, challenges to all-optical methods. An essential prerequisite is an optical potential whose depth is sufficiently greater than the temperature of the atoms being loaded. The usual starting point is a laser cooled atomic gas confined to a magneto-optical trap (MOT). In a twolevel picture, atoms may be cooled to the Doppler limit T D =h /(2k B ), where /(2π ) is the natural linewidth of the excited state of the cooling transition [7,8]. In many cases, however, sub-Doppler temperatures can be realized due to the occurrence of polarization gradient cooling arising from the multilevel character of real atoms [9]. Polarization gradient cooling mechanisms are effective if the linewidth of the cooling transition is small compared to the hyperfine splitting of the excited state, or if there is a large degree of magnetic degeneracy in the ground state [10]. The limit to cooling in these cases is the recoil temperature T R =h 2 k 2 /(2mk B ), where k is the wave number of the laser cooling transition and m is the mass of the atom.Polarization gradient cooling is found to be efficient for most of the alkali-metal atoms including Na, Rb, and Cs; MOTs of these species routinely attain temperatures of ∼10 μK, which is not far above T R . Unfortunately, for Li and K, the elements most often employed in Fermi-gas experiments, sub-Doppler cooling is ineffective in the presence of magnetic fields, including those required for a MOT. For Li, sub-Doppler cooling is inhibited because the hyperfine splitting of the excited state is unresolved (Fig. 1), thus limiting ...