Website phishing is a cyberattack that targets online users for stealing their sensitive data containing login credential and banking details. The phishing websites appear very similar to their equivalent legitimate websites for attracting a huge amount of Internet users. The attacker fools the user by offering the masked webpage as legitimate or reliable for retrieving its important information. Presently, anti-phishing approaches necessitate experts to extract phishing site features and utilize third-party services for phishing website detection. These techniques have some drawbacks, as the requirement of experts for extracting phishing features is time consuming. Many solutions for phishing websites attack have been presented, such as blacklist or whitelist, heuristics, and machine learning (ML) based approaches, which face difficulty in accomplishing effectual recognition performance due to the continual improvements of phishing technologies. Therefore, this study presents an optimal deep autoencoder network based website phishing detection and classification (ODAE-WPDC) model. The proposed ODAE-WPDC model applies input data pre-processing at the initial stage to get rid of missing values in the dataset. Then, feature extraction and artificial algae algorithm (AAA) based feature selection (FS) are utilized. The DAE model with the received features carried out the classification process, and the parameter tuning of the DAE technique was performed using the invasive weed optimization (IWO) algorithm to accomplish enhanced performance. The performance validation of the ODAE-WPDC technique was tested using the Phishing URL dataset from the Kaggle repository. The experimental findings confirm the better performance of the ODAE-WPDC model with maximum accuracy of 99.28%.