Ytterbium
and erbium codoped crystals have attracted considerable
interest in the application of eye-safe laser, upconversion laser,
and low-loss optical communication. Despite the lithium niobate (LiNbO3, LN) single crystal has been accepted as an ideal crystal
matrix for Yb3+ and Er3+ ions possessing significant
application potential in self-upconversion laser, the Yb and Er codoped
near-stoichiometric LN (NSLN) crystal has rarely been studied. This
is due to the difficulty of the NSLN crystal growth compared with
that of the congruent LN (CLN). In this paper, an Yb, Er codoped near-stoichiometric
LN (Yb, Er:NSLN) crystal was grown by the Czochrolski method for the
first time. Spectra studies showed the constrained peak splitting
at 378, 526, and 650 nm of the Yb, Er:NSLN crystal compared with Yb,
Er:CLN crystal. It was attributed to the low concentration of intrinsic
defects which constrained the Stark-split of the three energy levels
of 4G11/2, 2H11/2, and 4F9/2 energy states. Some spectral changes are verified
induced by the stoichiometric composition in the polarized emission
spectra. The Yb, Er:NSLN crystal has high potential in upconversion
laser application.