Abstract:X 2 Sn=Sn: (X = H, Me, F, Cl, Br, Ph, Ar, …) are new species of chemistry. The cycloaddition reaction of X 2 Sn=Sn: are new study field of stannylene chemistry. To explore the rules of cycloaddition reaction between X 2 Sn=Sn: and the symmetric π-bonded compounds, the cycloaddition reactions of H 2 Sn=Sn: and ethylene were selected as model reactions in this paper. The mechanism of cycloaddition reaction between singlet H 2 Sn=Sn: and ethylene has been first investigated with the MP2/GENECP (C, H in 6-311++G**… Show more
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