2012
DOI: 10.1115/1.4005703
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Feedstock Diffusion and Decomposition in Aligned Carbon Nanotube Arrays

Abstract: Feedstock diffusion and decomposition in the root growth of aligned carbon nanotube (CNT) arrays is discussed. A nondimensional modulus is proposed to differentiate catalystpoisoning controlled growth deceleration from one which is diffusion controlled. It is found that, at current stage, aligned multi-walled carbon nanotube (MWNT) arrays are usually free of feedstock diffusion resistance. However, for single-walled carbon nanotube (SWNT) arrays, since the inter-tube distance is much smaller than the mean free… Show more

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“…This is also plausibly due to incompatible of catalysts deposition in our system by means of oxidized metal due to the presence of O2 in plasma, and low amount of ethanol introduction. Since ethanol could be decomposed at high temperature into acetylene, water and some other molecule species [10,11], the role of acetylene on nanotube growth has been then demonstrated [12]. Meaning that acetylene could be used to efficiently grow CNTs, whereas water could prolong the catalyst lifetime.…”
Section: Resultsmentioning
confidence: 99%
“…This is also plausibly due to incompatible of catalysts deposition in our system by means of oxidized metal due to the presence of O2 in plasma, and low amount of ethanol introduction. Since ethanol could be decomposed at high temperature into acetylene, water and some other molecule species [10,11], the role of acetylene on nanotube growth has been then demonstrated [12]. Meaning that acetylene could be used to efficiently grow CNTs, whereas water could prolong the catalyst lifetime.…”
Section: Resultsmentioning
confidence: 99%