We study the baryon-baryon interactions with strangeness S = −2 and corresponding momentum correlation functions in leading order covariant chiral effective field theory. The relevant low energy constants are determined by fitting to the latest HAL QCD simulations, taking into account all the coupled channels. Extrapolating the so-obtained strong interactions to the physical point and considering both quantum statistical effects and the Coulomb interaction, we calculate the ΛΛ and Ξ − p correlation functions with a spherical Gaussian source and compare them with the recent experimental data. We find a remarkable agreement between our predictions and the experimental measurements without introducing any free parameters, which demonstrates the consistency between theory, experiment, and lattice QCD simulations. Finally, we predict the ΣΣ (I = 2) interaction and corresponding momentum correlation function, which rules out the existence of a bound state in this channel. Future experimental measurement of the predicted momentum correlation function will provide a non-trivial test of not only SU(3) flavor symmetry and its breaking but also covariant chiral effective field theory.