To cite this version:A. Semerok, Christophe Dutouquet. Analytical performances of laser-induced micro-plasma of Al samples with single and double ultrashort pulses in air and with Ar-jet : A comparative study. Spectrochimica Acta Part B: Atomic Spectroscopy, Elsevier, 2014Elsevier, , 99, pp.163-171. 10.1016Elsevier, /j.sab.2014 A C C E P T E D M A N U S C R I P T
ACCEPTED MANUSCRIPT
Abstract.Ultrashort pulse laser microablation coupled with optical emission spectroscopy was under study to obtain several micro-LIBS analytical features (shot-to-shot reproducibility, spectral line intensity and lifetime, calibration curves, detection limits). Laser microablation of Al matrix samples with known Cu-and Mg-concentrations was performed by single and double pulses of 50 fs and 1 ps pulse duration in air and with Ar-jet.The micro-LIBS analytical features obtained under different experimental conditions were characterized and compared. The highest shot-to-shot reproducibility and gain in plasma spectral line intensity were obtained with double pulses with Ar-jet for both 50 fs and 1 ps pulse durations. The best calibration curves were obtained with 1ps pulse duration with Ar-jet. Micro-LIBS with ultrashort double pulses may find its effective application for surface elemental microcartography.