In a Dirac nodal line semimetal, the bulk conduction and valence bands touch at extended lines in the Brillouin zone. To date, most of the theoretically predicted and experimentally discovered nodal lines derive from the bulk bands of two-and three-dimensional materials. Here, based on combined angle-resolved photoemission spectroscopy measurements and first-principles calculations, we report the discovery of node-line-like surface states on the (001) surface of LaBi. These bands derive from the topological surface states of LaBi and bridge the band gap opened by spin-orbit coupling and band inversion. Our first-principles calculations reveal that these "nodal lines" have a tiny gap, which is beyond typical experimental resolution. These results may provide important information to understand the extraordinary physical properties of LaBi, such as the extremely large magnetoresistance and resistivity plateau.Topological semimetals represent a novel class of quantum materials whose conduction and valence bands touch at discrete points or extended lines [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18]. Until now, three types of topological semimetals have been discovered: Dirac, Weyl and nodal line. In Dirac/Weyl semimetals, the energy-momentum dispersion is linear along all momentum directions, forming Dirac/Weyl cones in the proximity of the Fermi level. In nodal line semimetals, the crossing points form extended lines in the momentum space, i.e., the nodal lines [5][6][7][8][9][10][11][12][13][14][15][16][17]. While the Dirac cones or nodal lines discovered in topological semimetals typically derive from the bulk bands, an interesting question is that whether they can exist as surface states of three-dimensional crystals. The nodal line surface states could manifest extraordinary properties that are distinct from other two-dimensional Dirac materials [18][19][20]. To date, the surface Dirac cones have already been extensively studied in topological insulators, such as the Bi 2 Se 3 family materials[21-23], while theoretical and experimental studies on the surface nodal lines are still rare [12].Recently, rare-earth monopnictide LaBi has been predicted to be a topological insulator based on firstprinciples calculations [24]. Moreover, magneto-transport measurements showed that LaBi hosts extremely large magnetoresistence (XMR) [25][26][27], in analogy to some topological semimetals, such as Cd 3 As 2 [28, 29], TaAs[30], and ZrSiS[31, 32]. These results have stimulated great research interest to search for the Dirac bands in LaBi. Recent angle-resolved photoemission spectroscopy (ARPES) measurements revealed that there are multiple surface Dirac cones on the (001) surface of LaBi[33-36]. However, the details of the band structures are still controversial. J. Nayak et al.[33] and X. H. Liu et al.[35] reported two surface Dirac cones at theX point with an energy separation of 75 meV and 80 meV, respectively. In contrast, R. Lou et al. [36] reported only one Dirac cone at theX point. Therefore, clarifyi...