2020
DOI: 10.26434/chemrxiv.12370406.v1
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Ferro-Self-Assembly: Magnetic and Electrochemical Adaptation of a Multiresponsive Zwitterionic Metalloamphiphile Showing a Shape-Hysteresis Effect

Abstract: We report on a novel multi-stimuli-responsive amphiphile, 1-(<i>Z</i>)-heptenyl-1’-dimethylammonium-methyl-(3-sulfopropyl)ferrocene<b> </b>(<b>6</b>), whose self-assembly properties can be altered by three different stimuli, namely: (i) the addition of external salts which serve to unfold the sultone headgroup, thus triggering self-assembly of <b>6</b> into vesicles; (ii) oxidation to <b>6<sup>+</sup></b>, which changes the lipophilic ferr… Show more

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