Ferrocene as an efficient and recyclable heterogeneous catalyst for catalytic ozonation in water

Lin, Kun‐Yi Andrew; Lin, Tien-Yu; Chen, Yu-Chien; Lin, Yi‐Feng

doi:10.1016/j.catcom.2017.03.004

Cited by 18 publications

(8 citation statements)

References 36 publications

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“…(nano-MgO@CNT@Gr)-S + O 3 / (nano-MgO@CNT@Gr)-S O] O-O / MgO ÀS Oc + O 2 (13) (nano-MgO@CNT@Gr)-S Oc + 2H 2 O + O 3 / (nano-MgO@CNT@Gr)-S (cOH) 2 + 3cOH + 2O 2 (14) (nano-MgO@CNT@Gr)-S (cOH) 2 + diazinon / CO 2 + H 2 O + intermediate (15) (nano-MgO@CNT@Gr) Àdiazinon + cOH / CO 2 + H 2 O + intermediate (16) where S in (nano-MgO@CNT@Gr)-S represents Lewis acid sites on the nano-MgO@CNT@Gr particle surface. According to the results from TBA experiments, it can be concluded that cOH indirect reactions are the major mechanism involved in diazinon degradation in the COP, as shown in the reaction presented in eqn (16).…”

Section: Catalytic Mechanismmentioning

confidence: 99%

“…14 Hydroxyl radicals, nonselective radicals with an excellent oxidation potential (2.80 eV) derived from ozone decomposition, have a stronger oxidizing capacity than ozone (2.07 eV) and so have greater efficiency than ozone for the degradation of recalcitrant compounds. 14,15 Also, O 3 directly reacts with the intermediates derived from organic materials in catalytic reactions, therefore demonstrating higher selectivity and removal efficiency towards organic pollutants. 9,14 Catalytic ozonation can be separated into two categories: homogeneous and heterogeneous.…”

Section: Introductionmentioning

confidence: 99%

“…14,15 Also, O 3 directly reacts with the intermediates derived from organic materials in catalytic reactions, therefore demonstrating higher selectivity and removal efficiency towards organic pollutants. 9,14 Catalytic ozonation can be separated into two categories: homogeneous and heterogeneous. 10 Transition metals have been used in homogeneous catalytic ozonation processes.…”

Section: Introductionmentioning

confidence: 99%

“…10 Transition metals have been used in homogeneous catalytic ozonation processes. 16 Many synthesized catalysts, such as metal oxides, 14,17,18 metal oxides coated on various supports, 14,19,20 and porous materials, 16,19,21 have been used in heterogeneous catalytic ozonation processes. Heterogeneous catalytic ozonation is considered to encourage advanced oxidation processes in water and wastewater treatment.…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

The catalytic ozonation of diazinon using nano-MgO@CNT@Gr as a new heterogenous catalyst: the optimization of effective factors by response surface methodology

et al. 2020

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Section: Catalytic Mechanismmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

The catalytic ozonation of diazinon using nano-MgO@CNT@Gr as a new heterogenous catalyst: the optimization of effective factors by response surface methodology

et al. 2020

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“…Ferrocene itself catalyzes benzene hydroxylation [5]. Mild and reversible redox process Fe II /Fe III makes ferrocene a suitable catalyst of Fenton-like reactions, which are utilized for degradation of organic contaminants in wastewater e.g., dye pollutants or residual antibiotics [6][7][8]. Ferrocene and several acyl-substituted derivatives were used as photoinitiators for anionic polymerization of alkyl α-cyanoacrylate [9,10].…”

Section: Introductionmentioning

confidence: 99%

Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints

et al. 2020

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The effect of modification of benzoylferrocene periphery on catalytic activity toward drying of alkyd resins has been investigated by the combination of experimental techniques. A series of substituted ferrocenes have been synthesized and characterized by analytical and spectroscopic tools including X-ray diffraction analysis on single crystals. The electrochemical behavior of the ferrocene derivatives has been elucidated by cyclic voltammetry and rotation disk voltammetry. The activity toward room temperature curing of alkyd resin has been evaluated by standard mechanical tests on coated plates, which enabled to establish a structure/catalytic activity relationship. Fast drying of test coatings has been observed for formulations of (3-methoxybenzoyl) ferrocene. Time-resolved infrared spectroscopy in combination with attenuated total reflectance sampling technique enabled to reveal the kinetic origin of the improved performance for this ferrocene derivative.

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Degradation of amaranth by persulfate activated with zero-valent iron: influencing factors, response surface modeling

et al. 2022

SN Appl. Sci.

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In this study, zero-valent iron (ZVI) is applied to activate persulfate (PDS) for the degradation of amaranth (AMR). The effects of PDS concentration, ZVI concentration, solution pH , temperature, and reaction time on the degradation of AMR by the ZVI/PDS advance oxidation process are investigated. Sulfate and hydroxyl radicals are involved in the main reaction pathway of AMR and sulfate radical acts as a dominant oxidant. The CCD (central composite design) plan is chosen to build the RSM model for the prediction of AMR degradation. ANOVA analysis shows that the secondary fitting model had great fitness with R2 = 0.997, $$R_{{{\text{adj}}}}^{2}$$ R adj 2 = 0.936, p-value of lack of fit = 0.107. Optimum conditions for 98% AMR removal given by RSM are PDS concentration = 7.33 mM, ZVI dosage = 17.79 mM, initial pH 4.62, temperature = 59.49 °C, reaction time = 9.88 min which is proved to be very closed to the real removal rate of 96.78%. Sensitivity analysis indicates that the relative importance of the influencing parameters is of the following order: temperature, PDS concentration, pH , ZVI dosage, and reaction time. The PDS/ZVI system shows an acceptable RSE of about 75% and TOC removal of 85% on AMR oxidation. Finally, the possible pathway of AMR degradation is proposed.

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Ferrocene as an efficient and recyclable heterogeneous catalyst for catalytic ozonation in water

Cited by 18 publications

References 36 publications

The catalytic ozonation of diazinon using nano-MgO@CNT@Gr as a new heterogenous catalyst: the optimization of effective factors by response surface methodology

The catalytic ozonation of diazinon using nano-MgO@CNT@Gr as a new heterogenous catalyst: the optimization of effective factors by response surface methodology

Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints

Degradation of amaranth by persulfate activated with zero-valent iron: influencing factors, response surface modeling

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