Ferrocenyl thiazolidine-2-thione ornamented 1D coordination polymers derived from coinage metal halides and pseudohalides

Abstract

Two new Cu(I) and one Ag(I) coordination polymers have been synthesized using ferrocenyl funtionalized ligand 3-ferrocenyl methyl-thiazolidine-2-thione (L). These polymers composed of [CuCN(L)]n (FcCuCN), [AgCN(L)]n (FcAgCN) and [{CuI(L)}2]n.nCHCl3 (FcCuI) have...

Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and DFT Calculations of the New Binuclear Copper(I) Complex Containing 2-Benzimidazolethiole and Triphenylphosphine Ligands

“…13 However, an incredible variety of complexes, ranging from mononuclear three-or four-coordinate thiones with square planar and tetrahedral Cu(I), respectively, to dimers with distorted tetrahedral geometry, are produced by bridging thione ligands through sulfur atoms. 14,15 For decades, mixed-ligand complexes have pinched a lot of attention as a result of their serious function in biological processes. Numerous studies [16][17][18][19][20][21][22] have discussed the production and spectral investigation of mixed-ligand complexes.…”