2670 wileyonlinelibrary.com water droplet; [ 6 ] trichomes on the leaf surface are arranged with orientation to direct water droplets toward one end of the leaf to conserve water; [ 7 ] the wing surface of brown lacewing (Micromus tasmaniae) with microtrichia at different length-scale allow the insect to get through the wetted surfaces. [ 8 ] The above-mentioned surface all contain microscale geometry with special arrangement or topographies to infl uence the surface property. Specifi cally, leaf surface contains various trichomes that for some incline at an acute angle to guide water [ 7 ] while others retain water on leaves to improved photosynthetic environment. [ 9 ] Inspired by the peculiar trichome structures, this study attempted to adopt cone-shaped structures to systematically understand how the inclination of the trichome infl uences the wettability of leaves.Different strategies have been reported to obtain artifi cial microcone structures for the study of wetting property, including replica moulding, [ 2b , 10 ] laser irradiation, [11][12][13] reactive ion etching (RIE), [ 14,15 ] and chemical deposition. [ 16 ] However, the above methods are complicated or not fl exible enough to make microcones with tunable feature for our specifi c purpose. Previously, ferrofl uid-molding method, which made use of ferrofl uid as the master of the mother mold, has been demonstrated to fabricate microscale polymer arrays with controllable size. [ 17 ] In this study, we utilized the similar technique and further, modifi ed it for our particular purpose ( Figure 2 ). In the experiment, microcone structures with different inclination angle were generated by adjusting the direction of external magnetic fi eld applied to the ferrofl uid. Nickel thin fi lm was then deposited to give a nanoscale roughness layer. Wettability studies (contact angle, sliding angle) were analyzed, and the retention forces of droplet move against or along the orientation of cones were investigated.
Results and DiscussionTo create cone-shaped structures resembling trichomes of plants, ferrofl uid-molding method was adopted. [ 17 ] As shown in Figure 3 a, the ferrofl uid was divided into microdroplets due to magnetic hydrodynamic instability and were arranged by the magnetic disks to form a hexagonal pattern. As the external Learning from nature, a series of cone-shaped structures resembling trichomes of plants are fabricated by ferrofl uid molding to understand the infl uence of geometry on wettability. Experimentally, ferrofl uid microdroplets are generated under an external magnetic fi eld, and their shape can be changed from right cones into oblique cones by tilting the external magnetic fi eld. Followed by hard molds made with UV-curable tri(propylene glycol) diacrylate, polydimethylsiloxane microcones with different inclination angle ( θ ) are subsequently generated. Nickel thin fi lm is deposited onto the microcones to form micro/nano dual-scale structures. The largest contact angle (CA) is obtained in nickel-deposited right cones (CA = 1...