Field Application of a Rapid Spectrophotometric Method for Determination of Persulfate in Soil

Abstract

Remediation of hydrocarbon contaminated soils can be performed both in situ and ex situ using chemical oxidants such as sodium persulfate. Standard methods for quantifying persulfate require either centrifugation or prolonged settling times. An optimized soil extraction procedure was developed for persulfate involving simple water extraction using a modified disposable syringe. This allows considerable saving of time and removes the need for centrifugation. The extraction time was reduced to only 5 min compared to 15 min for the standard approach. A comparison of the two approaches demonstrated that each provides comparable results. Comparisons were made using high (93 g kg−1 soil) and low (9.3 g kg−1 soil) additions of sodium persulfate to a petroleum hydrocarbon-contaminated soil, as well as sand spiked with diesel. Recoveries of 95±1% and 96±10% were observed with the higher application rate in the contaminated soil and spiked sand, respectively. Corresponding recoveries of 86±5% and 117±19% were measured for the lower application rate. Results were obtained in only 25 min and the method is well suited to batch analyses. In addition, it is suitable for application in a small field laboratory or even a mobile, vehicle-based system, as it requires minimal equipment and reagents.

Removal of sulfanilic acid from wastewater by thermally activated persulfate process: oxidation performance and kinetic modeling

“…300 vs 40 μs lifetime) . can be effectively generated by activating persulfate (PS) . Activating PS can be achieved by various methods, such as heat, UV irradiation, microwave (MW), ultrasound (US) and transition metals (Eqns (1) and (2)).…”

“…9 SO •− 4 can be effectively generated by activating persulfate (PS). 10,11 Activating PS can be achieved by various methods, such as heat, UV irradiation, microwave (MW), ultrasound (US) and transition metals (Eqns (1) and (2)). [12][13][14][15] Among these activated methods, thermally activated persulfate (TAP) has been suggested as a clean source of SO •− 4 and has been applied to study the degradation mechanisms of numerous emerging contaminants in water because of the simplicity of the system.…”