This report has been reproduced directly from the best availattie copy.Available to DOE and DOE contractors . . ( H 2 0 2 ) , if applied at sufficient loadings to contaminated soils, can effectively oxidize trichloroethylene (TCE) and perchloroethylene (PGE). Between the two oxidants, KMn04 is more stable and may result in a higher rate of TCE degradation.
LIST OF TABLESIn 1996, researchers at Oak Ridge National Laboratory ( O N ) proposed an oxidant delivery technique involving injection and recirculation of the oxidant solution into a contaminated aquifer through multiple horizontal and vertical wells. This technique would be applicable to saturated, hydraulically conductive formations. In the spring of 1997, the Department of Energy (DOE) at the Portsmouth Gaseous Diffusion Plant (PORTS) agreed to collaborate with the DOES Subsurface Contaminants Focus Area to conduct a field-scale treatability study using in situ chemical oxidation through recirculation (ISCOR). PORTS agreed to support the demonstration at the X-701B site where the technology can potentially be used to remediate TCE-contaminated groundwater and sediments. The ISCOR field demonstration took advantage of existing infrastructure and extensive site characterization data generated from previous field demonstrations at X-701B. The field test was implemented using a pair of previously installed horizontal wells that transect an area of DNAPL contamination. Groundwater was extracted from one horizontal well, pumped to an existing pump and treat facility, dosed with KMnO4, and re-injected into a parallel horizontal well approximately 90 ft away. The field demonstration lasted approximately one month. Treatment effectiveness was determined by comparing contaminant levels in pre-treatment, during, and post-treatment groundwater samples and preand post-treatment soil samples Analytical results from the field demonstration indicate that ISCOR is effective at oxidizing TCE in the saturated zone. Lateral and vertical heterogeneities within the Gallia impacted the ability to deliver oxidant solution uniformly throughout the area between the horizontal wells. Furthermore, TCE in the neighboring low-permeability formations (the Sunbury and Minford layers) was not affected by oxidant recirculation through the G a l l i a . The oxidant may not have had time to diffuse from the Gallia into the Sunbury or Minford formations given the short duration of this test. However, in general, TCE was not detected where oxidant was present in samples collected from Gallia monitoring wells within the test region. Reduction of the TCE mass within the more conductive Gallia formation will lead to an overall reduction of TCE mobility within the X-701B area. Long-term groundwater monitoring will be required to fully assess the impact of this demonstration on the ISCOR test region..
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ACKNOWLEDGMENTSThe planning and execution of the full-scale demonstration required the efforts of many individuals. The contributions of the following are recognized and appreciated.