2024
DOI: 10.3390/molecules29122810
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Field-Induced Slow Magnetic Relaxation in Mononuclear Cobalt(II) Complexes Decorated by Macrocyclic Pentaaza Ligands

Mengmeng Zeng,
Zeyu Ruan,
Siguo Wu
et al.

Abstract: Two cobalt(II) complexes [CoL1](OTf)2 (1, L1 = 6,6′′-di(anilino)-4′-phenyl-2,2′:6′,2′′-terpyridine) and [CoL2](OTf)2·MeOH (2, L2 = 6,6′′-di(N,N-dimethylamino)-4′-phenyl-2,2′:6′,2′′-terpyridine) were synthesized and characterized. Crystal structure analyses showed that the spin carries were coordinated by five N atoms from the neutral pentaaza ligands, forming distorted trigonal bipyramidal coordination environments. Ab initio calculations revealed large easy-axial anisotropy in complexes 1 and 2. Magnetic meas… Show more

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