Ceramic water filters (CWFs) are
produced globally using local
clay sources and can effectively remove bacterial pathogens during
point-of-use water treatment. The ceramic production process involves
firing clay mixed with burnout material at temperatures of 800–1100
°C, which induces mineralogical changes leading to increased
arsenic (As) leaching from CWF material compared to source clay. Unfired
clay and fired CWFs from Cambodia, Canada, and Mexico, CWF from Laos,
and test-fired clay from the United States were analyzed to determine
the extent of As leaching from CWFs that range in As (<1 to 16
mg kg–1) and iron (Fe) (0.6 to 5%) content. Deionized
water, NaOH, HCl, and oxalate extractions showed that firing increased
As solubility and decreased Fe solubility compared to unfired clay,
with up to 8 mg kg–1 of water-soluble As in Cambodian
CWFs. X-ray absorption spectra of the Cambodian clay and CWF showed
a decrease in the Fe–O distance from 2.01 to 1.91 Å and
decreased Fe coordination number from 6.3 to 4.6 after firing, indicating
a decrease in Fe–O coordination. Arsenic(V) was the dominant
species in Cambodia clay and CWF, existing primarily as a surface
complex with average As–Fe distance of 3.28 Å in clay
while in CWF As was either an outer-sphere As(V) phase or a discrete
arsenate phase with no significant As–Fe scattering contribution
within the resolution of the data. Improved understanding of molecular-scale
processes that cause increased As leaching from CWFs provides a basis
for assessing As leaching potential prior to CWF factory capital investment
as well as engineered solutions (e.g., modified firing temperature,
material amendments, and leaching prior to distribution) to mitigate
As exposure from CWFs.