Field test of a pre-pilot scale hollow fiber facilitated transport membrane for CO2 capture

Dai, Zhongde; Fabio, Santinelli; Marino, Nardelli Giuseppe; Costi, Riccardo; Deng, Liyuan

doi:10.1016/j.ijggc.2019.04.027

Cited by 46 publications

(13 citation statements)

References 44 publications

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“…The pilot field trials include the Norwegian University of Science and Technology (NTNU) and SINTEF’s tests at the SINTEF Tiller plant (Trondheim, Norway) [ 52 ], the Norcem cement factory (Brevik, Norway) [ 53 ], the Colacem cement plant (Gubbio, Italy) [ 54 , 55 ], and the Sines bituminous coal power station (Sines, Portugal) [ 56 ]. Helmholtz-Zentrum Geesthacht (HZG) has also undertaken a field test at a hard coal power station (Baden-Württemberg, Germany) [ 57 ], while the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) and the University of Melbourne (UM) have conducted their membrane separation trial at a lignite-fired power station (Victoria, Australia) [ 58 ].…”

Section: Membrane Scale-up Modular Fabrication and Field Testsmentioning

confidence: 99%

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Han

Yang

2020

Membranes

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CO2 capture from coal- or natural gas-derived flue gas has been widely considered as the next opportunity for the large-scale deployment of gas separation membranes. Despite the tremendous progress made in the synthesis of polymeric membranes with high CO2/N2 separation performance, only a few membrane technologies were advanced to the bench-scale study or above from a highly idealized laboratory setting. Therefore, the recent progress in polymeric membranes is reviewed in the perspectives of capture system energetics, process synthesis, membrane scale-up, modular fabrication, and field tests. These engineering considerations can provide a holistic approach to better guide membrane research and accelerate the commercialization of gas separation membranes for post-combustion carbon capture.

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Section: Membrane Scale-up Modular Fabrication and Field Testsmentioning

confidence: 99%

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Han

Yang

2020

Membranes

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“…A noticeable feature of the FTMs containing the mobile carriers is their facile fabrication into a flat-sheet [57][58][59] or hollow-fiber [55,60] configuration. Researchers at OSU have demonstrated the roll-to-roll continuous fabrication of the FTM containing PZEA-Sar as the mobile carrier ( Figure 10), which was rolled into prototype spiral-wound (SW) membrane modules with a membrane area up to 3 m 2 ( Figure 11).…”

Section: T a B L Ementioning

confidence: 99%

Recent advances in polymeric facilitated transport membranes for carbon dioxide separation and hydrogen purification

Han

2020

Journal of Polymer Science

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Membrane and membrane process have been widely considered as one of the best candidates for mitigating CO2 emissions from the combustion or utilization of fossil fuels. Various amine‐containing polymers constitute an important class of membranes, where the highly selective CO2 transport is achieved by the facilitated transport mechanism. In this review, the amine–CO2 chemistry is discussed in conjunction with the mechanism of the reaction‐mediated CO2 transport. A wide variety of amine‐containing polymers are discussed based on two synthesis motifs: (a) polyamines with amino groups covalently bound to the polymer backbone and (b) small molecule amines embedded in a polymer matrix. This review concludes with the remarks on the facilitated transport membranes for post‐combustion carbon capture (CO2/N2) and hydrogen purification (CO2/H2).

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“…where R' is an H atom or a different alkyl group from R. In the absence of H 2 O, reactions between CO 2 and sterically unhindered amines follow a zwitterion mechanism. 30,31 As described by Eqns (1) and 2, one amine reacts with CO 2 to form a zwitterion intermediate, which reacts with another amine subsequently to generate a carbamate. 32 In total, one CO 2 requires two amines.…”

Section: Gas Transport Mechanism In Aftmsmentioning

confidence: 99%

“…Carbon capture and storage (CCS) is considered as one of the effective solutions to combat global warming resulted from anthropogenic CO 2 emission 1 . CCS relies on CO 2 capture technology before its subsequent transportation and storage.…”

Section: Introductionmentioning

confidence: 99%

Water vapor effects on CO₂ separation of amine‐containing facilitated transport membranes (AFTMs) module: mathematical modeling using tanks‐in‐series approach

et al. 2020

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Amine-containing facilitated transport membranes (AFTMs) are emerging membranes and have great potential for CO 2 capture. AFTMs are particularly suitable for humid flue gases, as water vapor enhances the facilitated transportation of CO 2. However, there is a lack of mathematical models available to evaluate the impact of water vapor on CO 2 separation performance for large-scale membrane modules. Therefore, developing a mathematical model considering the water vapor effects is of great importance to guide the large-scale applications of AFTMs for CO 2 capture. In this study, a mathematical model using tanks-in-series approach for CO 2 capture through AFTMs is proposed. In this model, the tanks-in-series approach can reflect the variable (water vapor-dependent) gas permeance along the membrane module. Modeling results showed the necessity of considering the effect of water vapor content decline along the module. In addition, both increasing temperature and pressure primarily lead to a faster decline of relative humidity (RH) along the membrane module, resulting in an increase of CO 2 recovery but a decrease of CO 2 product purity. For a gas stream with relatively low water vapor content (<2% in this study), different H 2 O permeance has a minor effect on separation performance. Moreover, permeate gas with higher water vapor content as well as higher RH is considered more suitable for further treatment of second stage membrane separation. In conclusion,

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Field test of a pre-pilot scale hollow fiber facilitated transport membrane for CO2 capture

Cited by 46 publications

References 44 publications

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Recent advances in polymeric facilitated transport membranes for carbon dioxide separation and hydrogen purification

Water vapor effects on CO₂ separation of amine‐containing facilitated transport membranes (AFTMs) module: mathematical modeling using tanks‐in‐series approach

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Field test of a pre-pilot scale hollow fiber facilitated transport membrane for CO2 capture

Cited by 46 publications

References 44 publications

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

Recent advances in polymeric facilitated transport membranes for carbon dioxide separation and hydrogen purification

Water vapor effects on CO2 separation of amine‐containing facilitated transport membranes (AFTMs) module: mathematical modeling using tanks‐in‐series approach

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Water vapor effects on CO₂ separation of amine‐containing facilitated transport membranes (AFTMs) module: mathematical modeling using tanks‐in‐series approach