Fine Structure of Optical Energy Levels Scheme for Ni[sup 2+] Doped in Inverted Perovskite BaLiF[sub 3]

In this paper we review the spectroscopic properties of three transition metal ions - Mn4+, Cr3+ and Ni2+ - in crystals and establish a relationship between the energies of the lowest in energy spin-forbidden transitions and covalence of the “metal –ligand” chemical bonds. A new parameter β1=(BB0)2+(CC0)2 (where (B, C (B0, C0) are the Racah parameters of the ions in a crystal (free state), respectively) is shown to determine the energy of the above-mentioned transitions. The considered ions can be used as reliable probes of the covalent effects in various hosts. Several practical recommendations on how to tune the spin-forbidden transitions energy to meet specific needs are suggested.

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Fine Structure of Optical Energy Levels Scheme for Ni[sup 2+] Doped in Inverted Perovskite BaLiF[sub 3]

Cited by 2 publications

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Empirical relation between covalence and the energy position of the Ni2+ 1E state in octahedral complexes

Empirical relation between covalence and the energy position of the Ni2+ 1E state in octahedral complexes

Spin-Forbidden Transitions in the Spectra of Transition Metal Ions and Nephelauxetic Effect

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