Self-compacting concrete is quite commonly used in concrete-filled steel tube structures, but the compaction level of the self-compacting concrete, that is, the percentage of volume occupied by materials other than air void, within the steel tube is seldom investigated. The authors are of the view that the concrete mix proportions of the self-compacting concrete may have significant effects on the compaction level of the self-compacting concrete, which will be quantified by the ‘compaction index’ proposed in this study and thus the performance of the concrete-filled steel tube. Moreover, the mix proportions would also influence the performance of the concrete-filled steel tube by affecting the aggregate–aggregate and aggregate–paste interactions of the concrete, albeit this important issue is rarely addressed in previous studies either. Herein, a pilot study is conducted to investigate the influences of the self-compacting concrete mix proportions on the axial performance of concrete-filled steel tube. Four groups of concrete-filled steel tube specimens made with different self-compacting concrete were tested, and the investigated concrete mix parameters included the paste volume, fine to coarse aggregate ratio, and 9.5–19.0 mm aggregate ratio. It was found that the compaction index of the self-compacting concrete is a key factor enabling the successful use of self-compacting concrete in concrete-filled steel tube. Moreover, the paste volume and aggregate proportions of the concrete mix have certain effects on the post-peak behaviour and ductility of concrete-filled steel tube.