Using finiteness-related results for non-abelian tensor products, we prove finiteness conditions for the homotopy groups π n (X) in terms of the number of tensors. In particular, we establish a quantitative version of the classical Blakers-Massey triad connectivity theorem. Moreover, we study other finiteness conditions and equivalence properties that arise from the non-abelian tensor square. Finally, we give applications to homotopy pushouts, especially in the case of Eilenberg-MacLane spaces.