The hydrocarbon temperature–time curve is widely used instead of the standard curve to describe the temperature in the environment of structural surfaces exposed to fire in oil and gas chemical facilities and tunnels. This paper presents calculations of the ratio of time to reach critical temperatures at different nominal fire curves for steel structures such as bulkheads and columns with different types of fireproofing. The thermophysical properties of the fireproofing materials were obtained by solving the inverse heat conduction problem using computer simulation. It was found that the time interval for reaching critical temperatures in structures with different types of fireproofing in a hydrocarbon fire decreased, on average, by a factor of 1.2–1.7 compared to the results of standard fire tests. For example, for decks and bulkheads with mineral wool fireproofing, the K-factor of the ratio of the time for reaching the critical temperature of steel under the standard curve to the hydrocarbon curve was 1.30–1.62; for plaster, it was 1.56; for cement boards, it was 1.34; for non-combustible coatings, it was 1.38–2.0; and, for epoxy paints, it was 1.71. The recommended values of the K-factor for fire resistance up to 180 min (incl.) were 1.7 and, after 180 min, 1.2. The obtained dependencies would allow fireproofing manufacturers to predict the insulation thickness for expensive hydrocarbon fire experiments if the results of fire tests under standard (cellulosic) conditions are known.